Hydrogen separation membranes based on dense ceramic composites in the La27W5O55.5–LaCrO3 system

Dense Ceramic Membranes for Hydrogen Separation

In the 1980s and 1990s, the development of oxygen ion conductors for solid electrolytes, as well as mixed oxygen–electron conductors as electrodes for solid oxide fuel cells, brought scientists to envision a possibility of mixed-conducting oxygenpermeable ceramic membranes. Today this field is well established, and ceramic membranes are close to implementation in processes for oxygen extraction...

Dense Ceramic Membranes for Hydrogen Separation

Novel cermet (i.e., ceramic-metal composite) membranes have been developed for separating hydrogen from product streams that are generated during coal gasification, methane partial oxidation, and watergas shift reactions. The hydrogen permeation rate in the temperature range of 600-900°C has been measured for three classes (ANL-1, -2, and -3) of cermet membranes. ANL-3 membranes provided the hi...

Supported Dense Ceramic Membranes for Oxygen Separation

Microfabricated Palladium-based Membranes for Hydrogen Separation

An innovative process for the microfabrication of Pd-based membranes (Pd and Pd-Ag) on a <110> silicon wafer is presented. Pd-Ag alloy films containing 23wt% Ag are prepared by a dual-sputtering from pure Pd and Ag targets. In the first step, deep grooves are KOH etched in one side of a <110> oriented silicon wafer, leaving membranes with a thickness of ca. 50 μm. After Pd alloy deposition on t...

Development of Palladium-Alloy Membranes for Hydrogen Separation and Purification

This paper summarizes R&D activities and progress at NORAM Engineering and the University of British Columbia (UBC) on preparation and testing of thin palladium-based membranes and their applications. Most of these activities were carried out internally at NORAM, some jointly with UBC and their spin-off company, Membrane Reactor Technology (MRT) through a wide range of projects. Key results out...